Upgrading biogenic furans: blended C-10-C-12 platform chemicals via lyase-catalyzed carboligations and formation of novel C-12 - choline chloride-based deep-eutectic-solvents

作者：Donnelly Joseph^*; Mueller Christoph R; Wiermans Lotte; Chuck Christopher J; de Mara Pablo Dominguez

来源：Green Chemistry, 2015, 17(5): 2714-2718.

DOI：10.1039/c5gc00342c

Benzaldehyde lyase (BAL) results in an efficient biocatalyst for the umpolung carboligation of furfural, HMF, and mixtures of them, leading to blended C-10-C-12 platform chemicals. Subsequently, the mixing and gentle heating (<100 degrees C) of the formed hydroxy-ketone with choline chloride leads to the formation of a novel biomass-derived deep-eutectic-solvent.

• 出版日期2015