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摘要
An experimental investigation of quasireversible maximum (QRM) of azobenzene on mcrcury electrode by two methods, i.e.. traditional square-wave voltammetry (SWV) and fast Fourier transformed square-wave voltammetry (FT-SWV). was presented, and the influence factors on QRM of FT-SWV were discussed. The results show that the rate constants derived from FT-SWV agree with that of derived from traditional SWV with acceptable differences. showing a sound verification that the rate constants derived from FT-SWV were reliable. In addition, some theoretical predictions on FT-SWV were experimentally confirmed through the characterization of strongly adsorbed azobenzene on mercury film electrode. As a result, FT-SWV is further proved to be a powerful technique in kinetic studies of the Surface adsorbed processes.
