Post-Self-Assembly Cross-Linking of Molecular Nanofibers for Oscillatory Hydrogels

作者:Zhang Ye; Li Ning; Delgado Jorge; Gao Yuan; Kuang Yi; Fraden Seth; Epstein Irving R*; Xu Bing
来源:Langmuir, 2012, 28(6): 3063-3066.
DOI:10.1021/la203923d

摘要

After a polymerizable hydrogelator self-assembles in water to form molecular nanofibers, post-self-assembly cross-linking allows the catalyst of the Belousov-Zhabotinsky (BZ) reaction to be attached to the nanofibers, resulting in a hydrogel that exhibits concentration oscillations, spiral waves, and concentric waves. In addition to the first report of the observation of BZ spiral waves in a hydrogel that covalently integrates the catalyst, we suggest a new approach to developing active soft materials as chemical oscillators and for exploring the correlation between molecular structure and far-from-equilibrium dynamics.

  • 出版日期2012-2-14