Direct addition of supercritical alcohols, acetone or acetonitrile to the alkenes without catalysts

作者：Karnitanaka Takashi^*; Hikida Tatsuyoshi; Hayashi Satoshi; Kishida Nobuhiro; Matsuda Tomoko; Harada Tadao

来源：Tetrahedron Letters, 2007, 48(48): 8460-8463.

DOI：10.1016/j.tetlet.2007.09.159

• carbon-carbon bond forming reaction
• supercritical fluid
• hydroxyalkylation
• acetonylation
• uncatalyzed reaction

The reactions of the alkenes with supercritical organic compounds under non-catalytic conditions were investigated. The H and CR2OH, CH2C = OCH3 or CH2C N of supercritical alcohols (CHR2OH), acetone (CH3C = OCH3) or acetonitrile (CH3C N) added to the C = C bonds of alkenes form C-C bonds between the alpha-carbons of the supercritical organic compounds and the sp(2) carbons of the alkenes.

• 出版日期2007-11-26