A Co(II) complex based on a mixed N- and O-donor: synthesis, structural characterization, and properties

作者：Zhu, Xiao-Hong^*; Xia, Jing-Jing; Sang, Hai-Yun; Chen, Jing^*

来源：Zeitschrift Fur Naturforschung Section B-a Journal of Chemical Sciences, 2017, 72(3): 183-187.

DOI：10.1515/znb-2016-0226

• cobalt(II)
• coordination polymer
• magnetic interaction
• structural characterization

The hydrothermal reaction of 5,5'-[9pyridine3,5-dicarbonyl) bis(azanediyl)] diisophthalic acid (H4L) with a Co(II) salt yields the new complex: [Co-3(HL)(2)(H2O)(4)](1), which has been characterized by single crystal X-ray diffraction, IR, and elemental and thermogravimetric analyses. Complex 1 exhibits a binodal (4,8)-connected 2D net structure with (4(20).6(8))(4(6))(2) topology. The magnetic properties of 1 were also investigated.

• 出版日期2017-3
• 单位淮阴工学院