Adsorption and photocatalytic degradation of 2-CP in wastewater onto CS/CoFe2O4 nanocomposite synthesized using gamma radiation

作者：Abou Taleb M**** F^*

来源：Carbohydrate Polymers, 2014, 114: 65-72.

DOI：10.1016/j.carbpol.2014.07.061

• CoFe2O4
• Photocatalysis
• 2-Chlorophenol
• Degradation
• Gamma radiation

Photocatalytic degradation of 2-chlorophenol (2-CP) was studied using the photocatalyst chitosane/CoFe2O4 nanocomposite (CS/CF) under visible light. CS/CF nanocomposites were synthesized via gamma irradiation cross-linking method with the aid of sonication. Physical characteristics of CS/CF were studied using infrared spectrophotometer (IR), scanning electron microscopy (SEM), transmission electron microscope (TEM) and ultraviolet-visible (UV-vis) spectroscopy. Their photocatalytic activity was tested for the degradation of 2-CP in aqueous medium using sunlight. The effect of different parameters such as catalyst concentration, 2-CP concentration and reaction pH on degradation was also examined. It was verified that the 2-CP degradation rate fits a pseudo-first-order kinetics for initial 2-CP concentrations between 25 and 100 mg/l, at 30 degrees C. The degradation kinetics fit well Langmuir-Hinshelwood rate law. The degradation of (2-CP) follows pseudo-first-order kinetics. Results showed that after the catalyst had been used 5 times repeatedly, the degradation rate was still above 80%.

• 出版日期2014-12-19