A Novel Organic-Inorganic Complex Based on Monosodium-substituted Keggin Phosphotungstate and Copper(II)-Ethylenediamine Groups

作者:Ma Pengtao; Li Suzhi; Zhao Junwei; Wang Jingping*; Li Yan; Niu Jingyang
来源:Chemistry Letters, 2010, 39(2): 120-121.
DOI:10.1246/cl.2010.120

摘要

A novel organic-inorganic complex [Cu(en)(2)](3)[alpha-PW(11)NaO(39)]center dot 2H(2)O (1) was synthesized hydrothermally and characterized by elemental analyses, IR, UV. XPS, and X-ray single-crystal diffraction, constructed by monosodium-substituted Keggin phosphotungstates and copper(II)-ethylenediamine groups and formed a 6(5) center dot 8 CdSO(4)-like 3D framework.

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