A three-dimensional network constructed from the assembly of 1,3-diaminopropane-copper(II) and tetracyanopalladate(II) moieties

作者：Legendre Alexandre de Oliveira; Mauro Antonio Eduardo^*; Rodrigues de Oliveira Milene Aparecida; do Prado Gambardella Maria Teresa

来源：Inorganic Chemistry Communications, 2008, 11(8): 896-898.

DOI：10.1016/j.inoche.2008.04.031

• copper(II)
• coordination polymers
• tetracyanopalladate(II)
• 1,3-diaminopropane
• supramolecular chemistry
• hydrogen bonds

The coordination polymer [Cu(Pd(CN)(4))(pn)](n) (pn = 1,3-diaminopropane) has been synthesized and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The crystal structure showed that three cyano groups of each [Pd(CN)(4)] unit bridge Cu(II) centers leading to the formation of a three-dimensional network. A series of bifurcated hydrogen bonds between the amino groups of the diamine and the nonbridging cyano groups of the cyanometallate result in the organization of suprarnolecular chains and rings along the polymer.

• 出版日期2008-8