科研之友
微信
新浪微博
Facebook
分享链接
摘要
This article reports the nitration of Hydroxyl-Terminated Polybutadiene (HTPB) backbone by facile and efficient one pot procedure, resulting in the formation of conjugated nitro-alkene derivative of HTPB. The reaction was carried out with sodium nitrite and iodine. In order to optimization of the effective parameters on the synthesis of Nitro-HTPB, the proportional amounts of reactant, amount of solvent and temperature were investigated and the effect of these parameters on the nitration double bond on HTPB backbone was evaluated. The product Nitro-HTPB was characterized by FT-IR, H-1 NMR and C-13 NMR spectroscopy as well as DSC, and TG.
- 出版日期2018-6
