An Efficient Ruthenium Catalyst Bearing Tetradentate Ligand for Hydrogenations of Carbon Dioxide

作者：Zhang, Feng-Hua; Liu, Chong; Li, Wei; Tian, Gui-Long; Xie, Jian-Hua; Zhou, Qi-Lin^*

来源：Chinese Journal of Chemistry, 2018, 36(11): 1000-1002.

DOI：10.1002/cjoc.201800278

• carbon dioxide
• methanol
• formamide
• ruthenium
• hydrogenation
• reduction

A ruthenium complex with a tetradentate bipyridine ligand was proved to be a highly efficient catalyst for the conversions of CO2. Turnover numbers up to 300 000, 9800, and 2100 were achieved for the hydrogenations of CO2 to formamides, formamides to methanol and amines, and the direct hydrogenation of CO2 to methanol, respectively.

• 出版日期2018-11
• 单位南开大学