摘要

Using a quantum-corrected model, the optical cross section of a strongly coupled metallic nanowire dimer for variable separation widths of the junction between the nanowires is analysed by finite-different time-domain method. Numerical results show the classical electrodynamics fails to describe the coupling across sub-nanometer gaps, owing to non-local screening and the spill-out of electrons, where quantum effects become important. The quantum-corrected model approach models the junction between adjacent nanoparticles by means of a local dielectric response that includes electron tunnelling and tunnelling resistivity at the gap. The quantum-corrected model predicts optical properties in excellent agreement with fully quantum mechanical calculations for small interacting systems, opening a new venue for addressing quantum effects in realistic plasmonic systems.