A photo-induced excited state structure of a hetero-bimetallic ionic pair complex, Nd(DMA)(4)(H2O)(4)Fe(CN)(6)center dot 3H(2)O, analyzed by single crystal X-ray diffraction

作者：Svendsen Helle; Overgaard Jacob; Chen Yu Sheng; Iversen Bo B^*

来源：Chemical Communications, 2011, 47(33): 9486-9488.

DOI：10.1039/c1cc12626a

The excited state crystal structure of the ionic complex (Nd(DMA)(4)(H2O)(4)-Fe(CN)(6)center dot 3H(2)O (DMA = dimethylacetamide) has been determined at 15 K upon UV illumination by single crystal X-ray diffraction. Significant structural changes are observed around the Fe site in the excited state. These changes are similar to those observed for a related molecular compound exhibiting photomagnetic properties.

• 出版日期2011