A new mixed-valence copper(I,II) coordination polymer with 1-D chain structure

作者：Yu, Qing; Zhu, Li Gang; Bian, He Dong; Deng, Ji Hua; Bao, Xiao Ge; Liang, Hong^*

来源：Inorganic Chemistry Communications, 2007, 10(4): 437-439.

DOI：10.1016/j.inoche.2006.12.017

• mixed valence
• copper
• coordination polymers
• oxidation reactions
• hydrothermal reactions

A new mixed-valence copper(I,II) coordination polymer, {[(Cu2Cu2I2L4)-Cu-I-I-II] center dot 4DMF}(n) 1 (HL = N'-(2-methylene pyridine)ison-icotinohydrazide), was synthesized by N'-((N-oxide-pyridin-2-yl)methylene)isonicotinohydrazide and cuprous iodide. Complex I exhibit a one-dimensional structure built up from mixed valence units of (Cu2Cu2L4)-Cu-I-L-II linked by iodide anions. The coordinated environments of Cu(II) and Cu(I) are distorted octahedron and tetrahedron, respectively.

• 出版日期2007-4
• 单位广西师范大学; 玉林师范学院