Abrupt Spin Transition with Thermal Hysteresis of Iron(III) Complex [Fe-III(Him)(2)(hapen)]AsF6 (Him = Imidazole, H(2)hapen = N,N %26apos;-Bis(2-hydroxyacetophenylidene)ethylenediamine)

作者：Fujinami Takeshi; Koike Masataka; Matsumoto Naohide^*; Sunatsuki Yukinari; Okazawa Atsushi; Kojima Norimichi

来源：Inorganic Chemistry, 2014, 53(4): 2254-2259.

DOI：10.1021/ic402947u

The solvent-free spin crossover iron(III) complex [Fe-III(Him)(2)(hapen)]AsF6 (Him = imidazole, H(2)hapen = bis(2-hydroxyacetophenylidene)ethylenediamine), exhibiting thermal hysteresis, was synthesized and characterized. The Fern ion has an octahedral coordination geometry, with N2O2 donor atoms of the planar tetradentate ligand (hapen) and two nitrogen atoms of two imidazoles at the axial positions. One of two imidazoles is hydrogen-bonded to the phenoxo oxygen atom of hapen of the adjacent unit to give a hydrogen-bonded one-dimensional chain, while the other imidazole group is free from hydrogen bonding. The temperature dependencies of the magnetic susceptibilities and Mossbauer spectra revealed an abrupt spin transition between the high-spin (S = 5/2) and low-spin (S = 1/2) states, with thermal hysteresis.

• 出版日期2014-2-17