Application of the S=1 underscreened Anderson lattice model to Kondo uranium and neptunium compounds

作者：Thomas Christopher^*; da Rosa Simoes Acirete S; Iglesias J R; Lacroix C; Perkins N B; Coqblin B

来源：Physical Review B, 2011, 83(1): 014415.

DOI：10.1103/PhysRevB.83.014415

Magnetic properties of uranium and neptunium compounds showing the coexistence of the Kondo screening effect and ferromagnetic order are investigated within the Anderson lattice Hamiltonian with a two-fold degenerate f level in each site, corresponding to 5f(2) electronic configuration with S = 1 spins. A derivation of the Schrieffer-Wolff transformation is presented and the resulting Hamiltonian has an effective f-band term, in addition to the regular exchange Kondo interaction between the S = 1 f spins and the s = 1/2 spins of the conduction electrons. The resulting effective Kondo lattice model can describe both the Kondo regime and a weak delocalization of the 5f electrons. Within this model we compute the Kondo and Curie temperatures as a function of model parameters, namely the Kondo exchange interaction constant J(K), the magnetic intersite exchange interaction J(H), and the effective f bandwidth. We deduce, therefore, a phase diagram of the model which yields the coexistence of the Kondo effect and ferromagnetic ordering and also accounts for the pressure dependence of the Curie temperature of uranium compounds such as UTe.

• 出版日期2011-1-18