Mechanical and tribological properties of multi-element (AlCrTaTiZr)N coatings

作者:Lai Chia Han; Cheng Keng Hao; Lin Su Jien*; Yeh Jien Wei
来源:Surface and Coatings Technology, 2008, 202(15): 3732-3738.
DOI:10.1016/j.surfcoat.2008.01.014

摘要

Multi-element (AlCrTaTiZr)N coatings are deposited onto Si and cemented carbide substrates by reactive RF magnetron sputtering in an Ar+ N-2 mixture. The influence of substrate bias voltage, ranging from 0 to -200 V, on the microstructural, mechanical and tribological properties of these nitride coatings is studied. A reduction in concentration of N and Al is observed with increasing substrate biases. The (AlCrTaTiZr)N coatings show the face-centered-cubic crystal structure (B1-NaCl type). The use of substrate bias changes the microstructure of the (AlCrTaTiZr) N coating from the columns with microvoids in boundaries to the dense and less identified columns. The compressive macrostress increases from -0.9 GPa to -3.6 GPa with an increase of substrate bias. The hardness and adhesion increase to peak values of 36.9 GPa and 60.7 N at the bias voltage of -150 V, respectively. The tribological properties of the (AlCrTaTiZr)N coatings against 100Cr6 steel balls are evaluated by a ball-on-disc tribometer with a 10 N applied load. With an increase of substrate bias, the wear rate reduces while the friction coefficient almost keeps constant at 0.75. The lowest wear rate of 3.