Anion Probe and Molecular Logic Gate Based on Tryptanthrin Derivative

作者：Wang Qingguo; Li Dan; Lu Ning; Tong Dingyi; Zhuang Hejing; Li Fuqiu^*; Wang Lan; Duan Haifeng; Lin Yingjie

来源：Chemical Journal of Chinese Universities, 2014, 35(10): 2114-2118.

DOI：10.7503/cjcu20140090

• Anion
• Tryptanthrin
• Molecular logic gate

A tryptanthrin derivative as anions probe was synthesized by the reaction of tryptanthrin with phenylhydrazine. In DMF, with the addition of F-, AcO- and H2PO4-, the "yellow-to-orange" change could be observed by naked eyes. Meanwhile, there were no changes when other anions(Cl-, Br-, I-, ClO4-, NO3- and HSO4-) were added. H-1 NMR titrations of this anions probe indicated that the "yellow-to-orange" response was triggered by the hydrogen bonding interaction between NH with F-, AcO- and H2PO4-. Then a novel four-input molecular logic gate was designed.

• 出版日期2014-10-10
• 单位吉林大学