A high performance anion exchange membrane-type ammonia borane fuel cell

作者：Zhang Xin Bo; Yan Jun Min; Han Song; Shioyama Hiroshi; Yasuda Kazuaki; Kuriyama Nobuhiro; Xu Qiang^*

来源：Journal of Power Sources, 2008, 182(2): 515-519.

DOI：10.1016/j.jpowsour.2008.04.032

• ammonia borane
• fuel cell
• discharge performance
• cell stability
• fuel crossover

The electrochemical behavior of the novel fuel cell directly using aqueous ammonia borane (NH3BH3) as the fuel has been systematically investigated. The cell consists of an oxygen cathode and an ammonia borane solution fed anode, where the catalyst layers are made of Vulcan XC-72 with 46.6wt.% Pt. An anion exchange membrane is employed as the electrolyte. It is found that the concentrations of NH3BH3 solution and temperatures significantly affect the open circuit potentials of the anode as well as the cell performance. Although the cell voltages decrease with the increase of current densities, the cell is capable of discharging at a current density of 185 mA cm(-2) with the cell potential larger than 0.6V. The obtained high energy densities indicate that the direct ammonia borane fuel cell holds potential applications for portable devices.

• 出版日期2008-8-1