A simple route for preparation of textured WO3 thin films from colloidal W nanoparticles and their photoelectrochemical water splitting properties

作者：Emin S^*; de Respinis M; Fanetti M; Smith W; Valant M; Dam B

来源：Applied Catalysis B: Environmental , 2015, 166: 406-412.

DOI：10.1016/j.apcatb.2014.11.053

• Photoelectrochemical water splitting
• Colloidal nanoparticle
• Tungsten trioxide

Colloidal tungsten (W) nanoparticles (NPs) were synthesized by pyrolysis of W(CO)(6) precursor in a mixture of 1-octadecene, oleylamine and oleic acid at similar to 230 degrees C under Ar atmosphere. The metallic W NPs were spin-coated on fluorine-doped tin oxide (FTO) substrates and later were transformed to WO3 phase by heat treatment at 500 and 550 degrees C. We prepared WO3 thin films with different thicknesses which we used in photoelectrochemical water splitting. The highest achieved photocurrent was similar to 830 mu A/cm(2) at 1.9 V vs. reference reversible hydrogen electrode (RHE) with the 900 nm thick WO3 film. Incident photon-to-current conversion efficiency (IPCE) showed that the quantum efficiency of WO3 thin films can reach up to 66% at 320 nm. Characterization of W NPs and WO3 thin films was carried out with UV-vis absorption spectroscopy, diffused reflectance spectroscopy, X-ray diffraction, transmission electron microscope and scanning electron microscope. The procedure given herein is a novel fabrication approach for the preparation of textured WO3 thin films where metallic W NPs are used as a precursor material. The proposed method can be generalized and extended to the preparation of other types of textured metal oxide thin films.

• 出版日期2015-5