Assorted morphosynthesis: access to multi-faceted nano-architectures from a super-responsive dual pi-functional amphiphilic construct

作者：Asthana Deepak; Shukla Jyoti; Dana Srikanta; Rani Varsha; Ajayakumar M R; Rawat Kamla; Mandal Kalyanashis; Yadav Premlata; Ghosh Subhasis; Mukhopadhyay Pritam^*

来源：Chemical Communications, 2015, 51(83): 15237-15240.

DOI：10.1039/c5cc05198c

An electronically segmented amphiphile was created by conjugating two pi-functional units hydroxyquinoline and naphthalenediimide (HQ/NDI) for the first time. The differential electrostatic potential of the pi-surfaces, H-bonding units, etc. trigger a manifold response and direct the assembly of a unique collection of seven diverse nano-architectures. Chiral assembly, distinct classes of fibers, 3-D sheets, and metallo-spheres/fibrils with mu M levels of Co/Cu/Zn(II) ions emerged from this new approach of assorted morphosynthesis under ambient conditions.

• 出版日期2015