New pincer-type diphosphinito (POCOP) complexes of Ni-II and Ni-III

作者：Pandarus Valerica; Zargarian Davit^*

来源：Chemical Communications, 2007, (9): 978-980.

DOI：10.1039/b613812h

This communication reports the synthesis and characterization of the new, pincer-type, square-planar, 16-electron compounds {2,6-(OPP2i)(2)C6H3}(NiBr)-Br-II, 1, and {((P2POCH2)-P-i)(2)CH} (NiBr)-Br-II, 2, and the square-pyramidal, 17-electron complex {((Pr2POCH2)-P-i)(2)CH}(NiBr2)-Br-III,3.

• 出版日期2007-3-7