Analytical representations of the spread harmonic measure density

作者:Grebenkov Denis S*
来源:Physical Review E, 2015, 91(5): 052108.
DOI:10.1103/PhysRevE.91.052108

摘要

We study the spread harmonicmeasure that characterizes the spatial distribution of reaction events on a partially reactive surface. For Euclidean domains in which Brownian motion can be split into independent lateral and transverse displacements, we derive analytical formulas for the spread harmonic measure density and analyze its asymptotic behavior. This analysis is applicable to slab domains, general cylindrical domains, and a half-space. We investigate the spreading effect due to multiple reflections on the surface, and the underlying role of finite reactivity. We discuss further extensions and applications of analytical results to describe Laplacian transfer phenomena such as permeation through semipermeable membranes, secondary current distribution on partially blocking electrodes, and surface relaxation in nuclear magnetic resonance.

  • 出版日期2015-5-7