Alternating ring-opening copolymerization of styrene oxide and maleic anhydride using asymmetrical bis-Schiff-base metal(III) catalysts

作者：Liu, Dengfeng^*; Zhang, Xingmei; Zhu, Luqun; Wu, Jing; Lu, Xingqiang

来源：Catalysis Science & Technology, 2015, 5(1): 562-571.

DOI：10.1039/c4cy01064g

• MALDI-TOF-MS
• ALUMINUM PORPHYRIN
• COMPARTMENTAL LIGANDS
• PHTHALIC-ANHYDRIDE
• BETA-LACTONE
• POLYMERIZATION
• EPOXIDES
• CHO
• METALLOPORPHYRIN
• COMPLEXES

A ring-opening copolymerization of styrene oxide with maleic anhydride was performed by applying a series of asymmetrical bis-Schiff-base metal(III) catalysts. The chromium catalyst exhibited the best performance and therefore the catalyst (salen)CrCl (salen = 4-((Z)-(2-((E)-3,5-dibromo-2-hydroxybenzylideneamino) phenylimino)(phenyl) methyl)-1-(4-chlorophenyl)-3-methyl-1H-pyrazol-5(4H)-one) (7) was chosen for further studies. The investigations on the effect of different co-catalysts on the copolymerization of styrene oxide and maleic anhydride revealed that DMAP showed the highest activity, followed by PPN+Cl-, whereas Ph3P showed the lowest activity. H-1 NMR and MALDI-TOF-MS spectra of the copolymers formed confirmed the alternating microstructures. The copolymerization of styrene oxide with maleic anhydride bearing a double bond in its structure was shown to be highly dependent on the polymerization condition, type of co-catalyst, monomer to catalyst ratio, temperature and time used in the copolymerization reaction. Applying chain transfer agents, alcohols, resulted in a decrease in molecular weight.

• 出版日期2015
• 单位西安科技大学; 西北大学