Detailed Structure Analysis of Atomic Positions and Defects in Zirconium Metal-Organic Frameworks

作者：Oien Sigurd; Wragg David; Reinsch Helge; Svelle Stian; Bordiga Silvia; Lamberti Carlo; Lillerud Karl Petter^*

来源：Crystal Growth & Design, 2014, 14(11): 5370-5372.

DOI：10.1021/cg501386j

We report the structure of the Zr metalorganic frameworks (MOFs) UiO-66 and UiO-67 to very fine detail using synchrotron single-crystal X-ray diffraction and the synthesis method used to obtain single crystals. Zr terephthalate MOF UiO-66 is known to have missing linkers, and the nature of these are shown to be coordinating water and solvent molecules. Single crystals of the isoreticular material UiO-67 does not show such missing linker defects.

• 出版日期2014-11