A Series of [MnMo9O32](6-) Based Solids: Homochiral Transferred from Adjacent Polyoxoanions to One-, Two-, and Three-Dimensional Frameworks

作者：Tan, Huaqiao; Li, Yangguang^*; Chen, Weilin; Yan, Aixue; Liu, Ding; Wang, Enbo

来源：Crystal Growth & Design, 2012, 12(3): 1111-1117.

DOI：10.1021/cg2004936

• SPONTANEOUS RESOLUTION
• BUILDING-BLOCKS
• POLYOXOMETALATE CLUSTERS
• CHIRAL POLYOXOTUNGSTATES
• COBALT(III) COMPLEXES
• CRYSTAL-STRUCTURES
• SELF-ORGANIZATION
• 3D ARCHITECTURES
• ACID

Five new compounds based on the Waugh-type polyoxoanion [MnMo9O32](6-) Na4Mn[MnMo9O32]center dot 11.5H(2)O (1), KNa3Mn[MnMo9O32]center dot 9H(2)O (2), Na2Ni2[MnMo9O32]center dot 12H(2)O (3), L-Mn-3[MnMo9O32].13H(2)O (4a), D-[Mn-3[Mo9O32]center dot 13H(2)O (4b), and L-Ni-3[MnMo9O32]center dot 11.5H(2)O (5a) have been synthesized. in these compounds, with the changes of Na+/TM (TM = mn(2+), Ni2+) in the crystal, the homochiral interactions were extended from two adjacent [MnMo9O32](6-) to one-dimensional (compounds 1 and 2), two-dimensional (compound 3), and three-dimensional (compounds 4 and 5) systems, respectively.

• 出版日期2012-3
• 单位东北师范大学