A novel cobalt(II) metal-organic framework based on an unprecedented ribbon-shaped secondary building unit

作者:Meng, Wei*; Xu, Shuang; Zhang, Zhengrui; Yu, Shuqi; Yu, Jikang; Dai, Lei*; Wang, Ling; Hou, Hongwei
来源:Inorganic Chemistry Communications, 2016, 65: 45-48.
DOI:10.1016/j.inoche.2016.01.014

摘要

A novel 3D metal organic framework (MOF) {[Co-2.5(dcPP) (mu(3)-OH) (mu-H2O)] center dot H2O}(n) (H(4)dcpp = 4,5-bis(4'-carboxylphenyl)-phthalic acid) with unprecedented ribbon-shaped secondary building units (SBUs), has been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, and IR. In addition, the thermal stability and magnetic behavior of the complex were also investigated.