An organic cation as a silver(I) analogue for the arylation of sp(2) and sp(3) C-H bonds with iodoarenes

作者：Arroniz Carlos; Denis J Gabriel; Ironmonger Alan; Rassias Gerasimos; Larrosa Igor^*

来源：Chemical Science, 2014, 5(9): 3509-3514.

DOI：10.1039/c4sc01215a

Reactions promoted by stoichiometric amounts of silver salts suffer from high cost, limited availability and raise environmental concerns. This manuscript describes studies leading to the discovery of a general replacement for silver with an inexpensive and convenient organic salt in palladium catalyzed direct C(sp(2))-H and C(sp(3))-H arylation reactions.

• 出版日期2014-9