Aquachloro(4-cyanobenzoato-kappa O)-(1,10-phenanthroline-kappa N-2,N ')copper(II) monohydrate

作者:Zhou YL; He HY; Zhang Y; Zhu LG*
来源:Acta Crystallographica Section E-Structure Reports Online, 2003, 59: M605-M607.
DOI:10.1107/S1600536803015605

摘要

The reaction of copper(II) chloride with 4-cyanobenzoic acid and 1,10-phenanthroline in a mixture of dimethylformamide and methanol gives the title complex, [CuCl(C8H4NO2)-(C12H8N2)(H2O)].H2O. The Cu-II ion is coordinated by one 1,10-phenanthroline, one water molecule, one Cl atom, and one 4-cyanobenzoate ligand. In the crystal structure, there are O-H...Cl hydrogen bonds and pi-pi-stacking interactions.