A facile synthesis of uniform Ag nanoparticle decorated CVD-grown graphene via surface engineering

作者：You Sun Ah; Kwon Oh Seok; Jang Jyongsik^*

来源：Journal of Materials Chemistry, 2012, 22(34): 17805-17812.

DOI：10.1039/c2jm33589a

The fabrication of designable CVD-grown few-layer graphene is a promising research area for enhanced device performance. In this study, the few-layer graphene was grown on Cu foil by chemical vapour deposition (CVD) method and functionalized with oxygen plasma treatment under controlled conditions, such as exposure time, input power and distance between the graphene and the plasma electrode. Oxygen plasma treated few-layer graphene (OPFG) results in high surface energy, leading to effectively attracting Ag+ ions in electrostatic interactions. Interestingly, the distribution of the metal nanoparticles increased with increasing the exposure time and their diameters were controlled by UV irradiation. Uniform Ag nanoparticles (Ag NPs) with ca. 9 nm diameter were successfully decorated on the graphene surface. Moreover, the Ag NPs/OPFG nanocomposite (AgNP-G) film has excellent mechanical bendability and durability in a flexible system.

• 出版日期2012