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摘要
Reaction mechanisms of the copper-mediated amination of aryl halides with trimethylsilyl azide (TMSN3) were analyzed on the basis of the time-course study using reaction monitoring FT-IR, trapping an intermediary aryl azide by the Huisgen reaction, and the analysis of the generated N-2 gas during the reaction. This amination would proceed through multiple pathways via aryl radicals and copper(I) azide.
- 出版日期2013-9-20
