Azobenzenes as light-controlled molecular electronic switches in nanoscale metal-molecule-metal junctions

作者:Mativetsky Jeffrey M; Pace Giuseppina; Elbing Mark; Rampi Maria A; Mayor Marcel*; Samori Paolo
来源:Journal of the American Chemical Society, 2008, 130(29): 9192-+.
DOI:10.1021/ja8018093

摘要

Conductance switching associated with the photoisomerization of azobenzene-based (Azo) molecules was observed in nanoscopic metal-molecule-metal junctions. The junctions were formed by using a conducting atomic force microscope (C-AFM) approach. where a metallic AFM tip was used to electrically contact ago-supported Azo self-assembled monolayer. The measured 30-fold increase in conductance is consistent with the expected decrease in tunneling barrier length resulting from the conformational change of the Azo molecule.

  • 出版日期2008-7-23