Application of calcined waste fish (Labeo rohita) scale as low-cost heterogeneous catalyst for biodiesel synthesis

作者：Chakraborty R^*; Bepari S; Banerjee A

来源：Bioresource Technology, 2011, 102(3): 3610-3618.

DOI：10.1016/j.biortech.2010.10.123

• Calcined fish scale
• Heterogeneous catalyst
• Biodiesel
• Soybean oil
• RSM optimization

This paper explores the feasibility of converting waste Rohu fish (Labeo rohita) scale into a high-performance, reusable, low-cost heterogeneous catalyst for synthesis of biodiesel from soybean oil. The thermo-gravimetric analysis (TGA) and X-ray diffraction (XRD) analysis revealed that a significant portion of the main component of fish scale i.e. HAP (hydroxyapatite) could be transformed into beta-tri-calcium phosphate when calcined above 900 degrees C for 2 h. Scanning Electron Microscopy (SEM) morphology studies of the calcined scale depicted a fibrous layer of porous structure; while a BET surface area of 39 m(2)/g was measured. Response surface methodology (RSM) was employed to determine the optimal parametric conditions viz, methanol/oil molar ratio, 6.27:1, calcination temperature, 997.42 degrees C and catalyst concentration, 1.01 wt.% of oil corresponding to a maximum FAME yield of 97.73%. Reusability results confirmed that the prepared catalyst could be reemployed up to six times, procreating a potentially applicable avenue in biodiesel synthesis.

• 出版日期2011-2