A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap

作者：Chen Yang^*; Sokolow Jesse D; Trzop Elzbieta; Coppens Philip

来源：Dalton Transactions, 2013, 42(43): 15285-15287.

DOI：10.1039/c3dt52218k

A three-dimensional coordination polymer based on a manganese-doped polyoxotitanate nanocluster, {Ti13Mn4O16[MeC(CH2O)(3)](4)(OEt)(12)Br-4}(infinity), has been synthesized under solvothermal conditions. It is the first framework of doped polyoxotitanate nanoclusters reported in the literature. Compared with anatase, its band gap is reduced from 3.19 to 2.57 eV.

• 出版日期2013