Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

作者：Dube Jonathan W; Brown Zachary D; Caputo Christine A; Power Philip P; Ragogna Paul J^*

来源：Chemical Communications, 2014, 50(16): 1944-1946.

DOI：10.1039/c3cc48933g

The reaction of phosphine gas with a low coordinate diaryl germylene or diarylstannylene results in both oxidative addition and arene elimination at the group 14 atom. The products were characterised by P-31 NMR spectroscopy and X-ray crystallography, and represent the first P-H bond activation by a heavy group 14 element compound.

• 出版日期2014