Microwave pyrolysis of cellulose at low temperature

作者：Al Shra'ah Ahmad; Helleur Robert^*

来源：Journal of Analytical and Applied Pyrolysis, 2014, 105: 91-99.

DOI：10.1016/j.jaap.2013.10.007

• Microwave pyrolysis
• Cellulose
• Crystallinity
• Py-GC/MS
• Biochar
• Bio-oil

Microwave pyrolysis of cellulose was successfully achieved at low temperature (200-280 C) using a lab-scale microwave synthesis system. Both closed and open microwave setups were developed to measure yields of pyrolysis products and to characterize the bio-oil. The effect of temperature, type of cellulose (crystalline and amorphous), and microwave absorber were examined. Microwave-derived bio-oil compositions were compared to conventional pyrolysis (microfurnace pyrolyzer-GC/MS) under similar heating rates. Maximum bio-oil yield (45%) was obtained from amorphous cellulose at 260 C using an open system. Addition of water significantly increased the bio-oil yield to 52% (amorphous) and to 47% (crystalline) while addition of activated carbon had the effect of increasing gaseous products. Microwave-derived bio-oil products varied in chemical nature and abundance depending on cellulose crystallinity and between open or closed microwave pyrolysis and showed significant differences from conventional pyrolysis bio-oil. High yields of levoglucosan were obtained from amorphous cellulose at 260 C while conventional pyrolysis required a much higher temperature (400 C).

• 出版日期2014-1