A comparative study on Na2MnPO4F and Li2MnPO4F for rechargeable battery cathodes

作者：Kim Sung Wook; Seo Dong Hwa; Kim Hyungsub; Park Kyu Young; Kang Kisuk^*

来源：Physical Chemistry Chemical Physics, 2012, 14(10): 3299-3303.

DOI：10.1039/c2cp40082k

Electrochemical properties of A(2)MnPO(4)F (A = Na/Li) were investigated both experimentally and with first principles calculations. A new Li2MnPO4F phase was successfully synthesized for the first time. A one alkali metal ion reaction occurred reversibly within a reasonable voltage window and a two alkali metal ion reaction took place at higher voltages.

• 出版日期2012