X-ray and neutron diffraction studies on "Li4.4Sn"

作者：Lupu C; Mao JG; Rabalais JW; Guloy AM^*; Richardson JW

来源：Inorganic Chemistry, 2003, 42(12): 3765-3771.

DOI：10.1021/ic026235o

A chemical analysis and detailed structural characterization, using X-ray single crystal and neutron powder diffraction, of the binary lithium-tin compound "Li4.4Sn" is presented. Phase analyses and subsequent structural refinements result in the reformulation of "Li4.4Sn" as Li17Sn4. The lithium-rich binary phase crystallizes with a complex cubic structure in the space group F43m, with a = 19.6907(11) Angstrom, Z = 20. The improved crystal structure determination indicates well-defined lithium atom positions, some of which differ from those previously reported. The nearly Zintl phase Li17Sn4 exhibits poor metallic behavior similar to that of heavily doped semiconductors. Comparisons of the refined crystal structure with previously reported X-ray crystal structures associated with "Li4.4Sn" are discussed.

• 出版日期2003-6-16