A study on interfacial tension between flexible polymer and liquid crystal

作者:Wu, Youjun; Yu, Wei*; Zhou, Chixing
来源:Journal of Colloid and Interface Science, 2006, 298(2): 889-898.
DOI:10.1016/j.jcis.2005.12.064

摘要

The interfacial property in polymer-liquid crystal systems is quite different front flexible polymer-polymer Mixtures due to the anisotropic properties of liquid crystals. The apparent interfacial tension between a liquid crystal and a flexible polymer was measured by deformed droplet retraction method. The deformation and recovery of a single liquid crystal droplet dispersed in a poly(dimethylsiloxane) matrix were realized by a transient shear flow and observed by polarized optical microscope. The apparent interfacial tension of polymer-liquid crystal system was found to be greatly dependent on the temperature, initial droplet deformation and liquid crystal droplet size.