Diaquabis[5-(pyrazin-2-yl-kappa N-1)-1H-tetrazolato-kappa N-1]manganese(II) and diaquabis[5-(pyrazin-2-yl-kappa N-1)-1H-tetrazolato-kappa N-1]zinc(II)

作者：Luo, Jun^*; Zhang, Xin-Rong; Cui, Li-Li; Dai, Wei-Quan; Liu, Bao-Shu

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2006, 62: M614-M616.

DOI：10.1107/S010827010604457X

• COORDINATION POLYMERS
• CRYSTAL-STRUCTURES
• COMPLEXES
• TETRAZOLE
• LIGANDS
• WATER

The two new title complexes, [Mn(C5H3N6)(2)(H2O)(2)] and [Zn(C5H3N6)(2)(H2O)(2)], are isomorphous. In both compounds, the metal atom is located on an inversion center and is coordinated by four N atoms from two 5-(pyrazin-2-yl)-1H-tetrazolate anions in the basal plane and by two O atoms of water ligands in the apical positions to form a distorted octahedral geometry. Intermolecular hydrogen- bond interactions between the uncoordinated N atoms of the tetrazolate anions and the H atoms of the water molecules lead to the formation of a three-dimensional network.

• 出版日期2006-12
• 单位中国人民解放军第二军医大学