Highly porous graphitic biomass carbon as advanced electrode materials for supercapacitors

作者：Gong, Youning; Li, Delong; Luo, Chengzhi; Fu, Qiang; Pan, Chunxu^*

来源：Green Chemistry, 2017, 19(17): 4132-4140.

DOI：10.1039/c7gc01681f

• ELECTROCHEMICAL ENERGY-STORAGE
• TEMPLATED MESOPOROUS CARBONS
• SOLID-STATE SUPERCAPACITORS
• DOUBLE-LAYER CAPACITOR
• CATALYTIC GRAPHITIZATION
• ACTIVATED CARBON
• WASTE BIOMASS
• PERFORMANCE
• GRAPHENE
• NANOSHEETS

In this work, we established a one-step strategy to synthesize three-dimensional porous graphitic biomass carbon (PGBC) from bamboo char (BC), and studied its electrochemical performance as electrode materials for supercapacitors. Using potassium ferrate (K2FeO4) to fulfil the synchronous carbonization and graphitization of bamboo carbon, this method is less time-demanding, highly efficient and pollution-free, when compared with a conventional two-step strategy. The as-prepared PGBC sample possessed a porous structure with a large specific surface area (1732 m(2) g(-1)) and abundant micropores, as well as a high graphitization degree demonstrated by XRD and Raman. Further electrochemical measurements revealed that the PGBC electrode exhibited a high specific capacitance of 222.0 F g(-1) at 0.5 A g(-1), and the solid-state symmetric supercapacitor in an aqueous electrolyte (KOH/PVA) presented considerable synergetic energy-power output properties with an energy density of 6.68 W h kg(-1) at a power density of 100.2 W kg(-1), and 3.33 W h kg(-1) at 10 kW kg(-1). Moreover, the coin-type symmetric supercapacitor in an ionic liquid electrolyte (EMIM TFSI) delivered a higher energy density of 20.6 W h kg(-1) at a power density of 12 kW kg(-1). This approach holds great promise to achieve low-cost, green and industrial-grade production of renewable biomass-derived carbon materials for advanced energy storage applications in the future.

• 出版日期2017-9-7
• 单位武汉大学