摘要
The suitability of pentafluorophenyl (PFP) esters and PFP alkyl moieties for orthogonal dual functionalization of block copolymer segments is evaluated. While amidation followed by para-fluoro–thiol substitution is a viable reaction sequence, thiol-based substitution can occur on PFP esters at a high rate, thereby hampering the viability of the reverse sequence.
- 出版日期2016
- 单位Karlsruhe Institute of Technology(KIT); Karlsruhe Institute of Technology (KIT)