A coordination polymer consisting of two different one-dimensional copper(II) chains

作者：Wu Yang; Wang Wen Zhen^*; Ismayilov Rayyat Huseyn; Lee Gene Hsiang; Peng Shie Ming

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2014, 70(3): 285-+.

DOI：10.1107/S2053229614002472

• crystal structure
• copper(II) complex
• coordination polymer

The title compound, catena-poly[[[diaqua(methanol-kappa O)copper(II)]-mu-N-(4-methylpyrimidin-2-yl-kappa N-1)pyrazin-2-amine-kappa N-2(1):N-4] [[aqua(aqua/methanol-kappa O)(perchlorato-kappa O) copper(II)]-mu-N-(4-methylpyrimidin-2-yl-kappa N-1)pyrazin-2-amine-kappa N-2(1):N-4] tris(perchlorate) methanol monosolvate 1.419-hydrate], {[Cu(C9H9N5)(CH3OH)(H2O)(2)][Cu(C9H9N5)(ClO4)(CH3OH)(0.581)(H2O)(1.419)](ClO4)(3)center dot CH3OH center dot 1.419H(2)O}(n), is a one-dimensional straight-chain polymer of N-(4-methylpyrimidin-2-yl)pyrazin-2-amine (L) with Cu(ClO4)(2). The complex consists of two crystallographically independent one-dimensional chains in which the Cu-II atoms exhibit two different octahedral coordination geometries. The L ligand coordinates to two Cu-II centres in a tridentate manner, with the pyrazine ring acting as a bridge linking the Cu-II coordination units and building an infinite one-dimensional chain. Extensive hydrogen bonding among perchlorate anions, water molecules and L ligands results in three-dimensional networks.

• 出版日期2014-3
• 单位西安石油大学