Hydrothermal synthesis and crystal structure of a new 3D-supramolecular complex: phen(2)Zn-2N(3)

作者：Bi Jian Hong^*; Man Cui; Huang Zi Xian; Kong Ling Tao; Wang Hong Liang; Hu Nai Liang

来源：Asian Journal of Chemistry, 2008, 20(5): 3996-4000.

• zinc complex
• supramolecule
• crystal structure
• 1,10-phenanthroline

The complex phen(2)Zn-2N(3), where phen is 1,10-phenanthroline, has been synthesized and its crystal structure was determined by X-ray diffraction. Crystal data: orthorhombic, space group Fdd2, a = 8.2 05(2) angstrom, b = 11.052(3) angstrom, c = 12.508(3) angstrom, alpha = 82.852(6) deg, beta = 81.899 (6) deg, gamma = 73.086(7) deg, V = 1070.2(5) angstrom(3), Mr = 509.84, F(000) = 618, Z = 2, Dc = 1.582Mg/m(3), mu = 1.185 mm(-1). The final R1 = 0.0406 and wR2 = 0.0828 for 8261 observed reflections (I > 2 sigma(I)). Zinc(II) ion is coordinated by six atoms in a prolonged octahedron geometry. The compound is in 3-dimensional supramolecular state.

• 出版日期2008-6
• 单位合肥师范学院