Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

作者：Smalley Adam P^*; Reid David G; Tan Jin Chong; Lloyd Gareth O

来源：CrystEngComm, 2013, 15(45): 9368-9371.

DOI：10.1039/c3ce41332b

There are relatively few metal-organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.

• 出版日期2013