A Coordination Polymer With a (3,4)-Connected (6(2).8)(2)(6(2).8(4)) 3D Network: Synthesis, Crystal Structure and Luminescent Properties

作者：Liu, Guang-Xiang^*; Guo, Wei; Nishihara, Sadafumi; Ren, Xiao-Ming

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2012, 42(9): 1222-1226.

DOI：10.1080/15533174.2012.680092

• Cd(II) coordination polymer
• luminescence
• polycarboxylate
• topology

The 3D Cd(II) coordination polymer Cd-2(ODPA)(bpe)(py)(H2O)(2) (1) with 3,3',4,4'-oxydiphthalic acid (H(4)ODPA) and 1,2bis-(4-pyridyl)ethane (bpe) was synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectrum, and single-crystal X-ray diffraction techniques. X-ray crystallographic studies of 1 reveal that this metal-organic complex has an interesting (3,4)-connected 3D network with binary nodes. The Cd atoms are three-connected nodes and the ODPA ligands are four-connected nodes. Luminescent study indicates 1 has an emissive maximum at 408 nm in the solid state at room temperature.

• 出版日期2012
• 单位南京晓庄学院; 南京工业大学