A New 1,3,4-Oxadiazole-Based Hole-Transport Material for Efficient CH3NH3PbBr3 Perovskite Solar Cells

作者：Carli Stefano; Baena Juan Pablo Correa^*; Marianetti Giulia; Marchetti Nicola; Lessi Marco; Abate Antonio; Caramori Stefano; Graetzel Michael; Bellina Fabio; Bignozzi Carlo Alberto; Hagfeldt Anders

来源：Chemsuschem, 2016, 9(7): 657-661.

DOI：10.1002/cssc.201501665

• hole transport
• oxadiazole
• perovskite
• solar cells
• titania

A new hole-transport material (HTM) based on the 1,3,4-oxadiazole moiety (H1) was prepared through a single-step synthetic pathway starting from commercially available products. Thanks to a deep HOMO level, H1 was used as HTM in CH3NH3PbBr3 perovskite solar cells yielding an efficiency of 5.8%. The reference HTM (Spiro-OMeTAD), under the same testing conditions, furnished a lower efficiency of 5.1%. Steady-state and time-resolved photoluminescence of the thin films showed good charge-extraction dynamics for H1 devices. In addition, H1 shows a large thermal stability and completely amorphous behavior (as evaluated by thermal gravimetric analysis and differential scanning calorimetry).

• 出版日期2016-4-7