Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M '(O2CPh)(6)](bpa) (M = Co, Zn, M ' = Co, Cd): Their catalytic activity

作者：Lee Young Min; Song Young Joo; Poong Jung In; Kim Soo Hyun; Koo Hyo Geun; Lee Jung Ah; Kim Cheal^*; Kim Sung Jin; Kim Youngmee

来源：Inorganic Chemistry Communications, 2010, 13(1): 101-104.

DOI：10.1016/j.inoche.2009.10.028

• Heterometallic complex
• One-dimensional chain
• 1,2-Bis(4-pyridyl)ethane
• Transesterification

Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M2M'(O2CC6H5](n)(bpa)(n) (bpa = 1,2-bis(4-pyridyl)ethane, M2M' = Zn2CO (1), Zn2Cd (2), and Co2Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1-3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them.

• 出版日期2010-1