Addition of halide to pi-bond directly from aqueous NaX solution: a general strategy for installation of two different functional groups

作者:Pandit Palash; Gayen Krishnanka S; Khamarui Saikat; Chatterjee Nirbhik; Maiti Dilip K*
来源:Chemical Communications, 2011, 47(24): 6933-6935.
DOI:10.1039/c1cc11685a

摘要

Activation of pi-bond with organic Lewis acid and cationic surfactant mediated direct transfer of halides to alkyne and alkene are demonstrated to afford alpha,alpha-dihaloketones and other valuable synthons with outstanding selectivities.

  • 出版日期2011