Hydrothermal syntheses and crystal structures of two 4,4 '-biphenyldicarboxylate copper(II) complexes with 1,10-phenanthroline

作者：Zhang SY; Yu MX; Zhu LG^*

来源：Journal of Molecular Structure, 2004, 699(1-3): 101-104.

DOI：10.1016/j.molstruc.2004.05.012

• hydrogen bonding
• crystal structure
• copper complex
• diversity
• polymer

Two structurally diverse compounds, [Cu(Hbpdc)(2)(phen)] (1) and [Cu(bpdc)(phen)(H2O)](n) (2) (H(2)bpdc = 4,4-biphenyldicarboxylic acid, phen = 1,10-phenanthroline), were synthesized under hydrothermal conditions. Copper atom in 1 is four-coordinated to one bidentate phen ligand and two monodentate partly deprotonated 4,4'-biphenyldicarboxylates. As expected, the structure of 1 is a monomeric species and affords an extended two-dimensional hydrogen bonding architecture. Each copper atom in 2 is five-coordinated to one phen, one water molecule. and two bis-monodentate fully deprotonated 4,4'-biphenyldicarboxylates. Therefore, the structure of 2 is a one-dimensional chain.

• 出版日期2004-8-2
• 单位浙江大学