Highly Sensitive Fluorescent Probe for Selective Detection of Hg2+

作者:Ding, De-Gang*; Wang, Jian-Ling
来源:Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2016, 46(4): 507-511.
DOI:10.1080/15533174.2014.988805

摘要

A selective and sensitive chromogenic and fluorogenic dual signal responding fluoride-sensor (L), comprising the well-known rhodamine 6G fluorophore and 2,2-bipyridine was prepared and spectroscopically characterized. After mercury ion was added to the CH3CN solution of L, a color change from colorless to pink-red, which indicated that the sensor can serve as a sensitive naked-eye indicator for mercury ion. The high emission selectivity is due to the formation of L-Hg2+ 1:2 complex leads to spirocycle opening of L.

  • 出版日期2016-4-2
  • 单位河南大学; 河南牧业经济学院